7.7%+ dividend yields! Are these the best stocks to buy for passive income?

I’ve been scouring the FTSE 100 and FTSE 250 indices for great stocks to buy for a second income. Are these dividend yields too high for me to miss?

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These FTSE 100 and FTSE 250 shares offer dividend yields far above the average for UK shares. But are they top stocks to buy or simply value traps?

Imperial Brands

Created with Highcharts 11.4.3Imperial Brands Plc PriceZoom1M3M6MYTD1Y5Y10YALLwww.fool.co.uk

Tobacco titan Imperial Brands’ (LSE:IMB) 8% forward dividend yield makes it one of the highest yielders on the FTSE 100 today.

Should you invest £1,000 in Tritax Big Box right now?

When investing expert Mark Rogers has a stock tip, it can pay to listen. After all, the flagship Motley Fool Share Advisor newsletter he has run for nearly a decade has provided thousands of paying members with top stock recommendations from the UK and US markets. And right now, Mark thinks there are 6 standout stocks that investors should consider buying. Want to see if Tritax Big Box made the list?

See the 6 stocks

And unlike many UK shares in the current macroeconomic climate, the business looks in solid shape to meet current dividend forecasts. The predicted payout is covered almost two times over by expected earnings.

The addictive nature of Imperial Brands’ products gives profit (and by extension dividend) estimates extra robustness too. So does the strong customer loyalty that its brands like Winston and John Player Special command.

But this is a dividend stock I’m avoiding. I actually sold my holdings in the business several years ago. And since then its share price has cratered as anti-smoking regulation has ramped up across the globe.

Rules on the sale, marketing, and use of cigarettes and other combustible tobacco products are becoming commonplace. They’re exacerbating existing concerns over the health impact of smoking and limiting sales to new generations of smokers.

Unfortunately for Big Tobacco, legislators are also increasingly clamping down on next-generation products like e-cigarettes and tobacco heating products (THPs) as well. Australia is the latest country to ban recreational vaping in recent months to combat vape use among teenagers.

Imperial Brands has spent a fortune developing products like its Pulze thermal heated device. But doubts are rising over whether these new technologies will save the company’s bacon in an increasingly smoke-free society.

I expect the share price to continue shrinking as its market does. Not even the prospect of big dividends in the near term is enough to encourage me to invest.

Tritax Big Box REIT

Created with Highcharts 11.4.3Tritax Big Box REIT Plc PriceZoom1M3M6MYTD1Y5Y10YALLwww.fool.co.uk

Please note that tax treatment depends on the individual circumstances of each client and may be subject to change in future. The content in this article is provided for information purposes only. It is not intended to be, neither does it constitute, any form of tax advice.

I’d rather use any spare cash I have to buy more shares in Tritax Big Box REIT (LSE:BBOX). I opened a position here in 2020 and a 7.7% forward dividend yield is making me consider increasing my stake.

Tritax’s share price soared on 19 July thanks to better-than-expected inflation data. The bad news is that interest rates look set to keep rising, damaging the company’s growth plans as borrowing costs increase. However, the new consumer price inflation (CPI) suggests rates may not soar as high as experts had feared.

I think the FTSE 250 business is a great share to buy for passive income. Under real estate investment trust (REIT) rules, it is obliged to pay a minimum of 90% of annual profits from rental operations out in the form of dividends. This removes the chance of those who run the company from deciding to hold on to the cash or spend it on other things.

So as demand for large warehouse and distribution hubs picks up I think dividends here could grow strongly. Some of Tritax’s major clients include Amazon, Ocado and Morrisons. I expect the industry to grow strongly thanks to themes like the growth of e-commerce and automation.

But here’s another bargain investment that looks absurdly dirt-cheap:

Like buying £1 for 31p

This seems ridiculous, but we almost never see shares looking this cheap. Yet this Share Advisor pick has a price/book ratio of 0.31. In plain English, this means that investors effectively get in on a business that holds £1 of assets for every 31p they invest!

Of course, this is the stock market where money is always at risk — these valuations can change and there are no guarantees. But some risks are a LOT more interesting than others, and at The Motley Fool we believe this company is amongst them.

What’s more, it currently boasts a stellar dividend yield of around 10%, and right now it’s possible for investors to jump aboard at near-historic lows. Want to get the name for yourself?

See the full investment case

Should you invest, the value of your investment may rise or fall and your capital is at risk. Before investing, your individual circumstances should be assessed. Consider taking independent financial advice.

John Mackey, former CEO of Whole Foods Market, an Amazon subsidiary, is a member of The Motley Fool’s board of directors. Royston Wild has positions in Tritax Big Box REIT Plc. The Motley Fool UK has recommended Amazon.com, Imperial Brands Plc, Ocado Group Plc, and Tritax Big Box REIT Plc. Views expressed on the companies mentioned in this article are those of the writer and therefore may differ from the official recommendations we make in our subscription services such as Share Advisor, Hidden Winners and Pro. Here at The Motley Fool we believe that considering a diverse range of insights makes us better investors.

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